In order to only publish an ad to an existing ad set all you need to do is the following:
1. Ensure the ad/creative you wish to publish is visible in the 'Create ads' tab:
2. Navigate to the 'My campaigns' tab, select the relevant campaign and head to the 'Ad sets' section:
3. Select the relevant ad set and click on 'Actions', then 'Add creatives':
4. Enter a static or dynamic name for your ad:
5. Select your Facebook pixel and add your URL parameters if desired:
6. Preview your ad before publishing to the existing ad set:
Please note that the objective of the new creatives needs to match the objective of the existing campaigns/ad set.